Synthesis of titanium dioxide nanostructures and their effects on current-voltage (I-V) performance in dye sensitized solar cells

نویسندگان

  • R. Govindaraj
  • M. Senthil Pandian
  • P. Ramasamy
  • Sumita Mukhopadhyay
چکیده

Anatase phase TiO2 nanostructures (Nanoparticles and nanorods) were prepared by two different methods. The prepared samples were characterized with Powder X-ray diffraction (PXRD), Field emission scanning electron microscopy (FESEM), High resolution transmission electron microscopy (HRTEM), Brunauer-Emmett-Teller (BET) method and Barrett-Joyner-Halenda (BJH) analysis. The PXRD pattern shows that both the nanostructures are anatase phase with good crystalline nature. The morphological results show that the TiO2 nanorods have diameter of about ~ 25 nm and the length of ~ 100 nm. The TiO2 nanoparticles are spherical in shape with mesoporous property. The solar energy conversion efficiency (η) of the cell using nanoparticles with mesoporous structure was about 3.415 % with Jsc of 13.206 mA/cm 2 , Voc of 0.607 V and FF of 43 % ; while efficiency of the cell using nanorods reached 1.21 % with Jsc of 4.35 mA/cm 2 , Voc of 0.661V and FF of 42%.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of TiO2 nanorods with a microwave assisted solvothermal method and their application as dye-sensitized solar cells

Inthiswork, Titanium dioxide (TiO2) nanostructures have beensynthesized via amicrowave assisted solvothermalmethod using titanium tetraisopropoxide (TTIP),polyvinylpyrrolidone(PVP) and Ascorbic Acid (AA) in ethanol. The mole ratio ofPVP/AA was found to be critical in determining the morphology and crystal phaseof the final product. PVP/AA mole ratio varied from 1 up to 1...

متن کامل

Optical Studies and Photovoltaic Performance of Nanocrystalline Titanium Dioxide Sensitized with Local Dye

Nanocrystalline titanium (iv) oxide paste has been deposited on Fluorine doped tin oxide glass substrate by the blade method. The deposited film was subjected to thermal treatment to obtain an electrode foe a photo-electrochemical cell. The electrode was sensitized with prophyrin dye which was a local dye extracted from carica papaya leaves. Avaspec 2.1 spectrophotometer was used to obtain the ...

متن کامل

Effect of Hydroquinone Dderivatives in Electrolytes on Dye-Sensitized Solar Cell Performance

New kinds of hydroquinone derivatives were synthesized and along with a azo dye applied as additives in the iodide/iodine redox electrolyte for dye-sensitized solar cells and their effect on the short-circuit photocurrent of dye sensitized solar cells was investigated. Addition of 0.05 M a hydroquinone derivative in the electrolyte comprising 0.5 M 1-methyl-3-propylimidazolium iodide (MPII) and...

متن کامل

Effects of Sensitization with Natural Pigments on the Performance of Dye-sensitized Solar Cell (DSSC)

Three natural pigments including wild iris, black pomegranate bark and black grapes were used as sensitizer in dye sensitized solar cells (DSSCs) based on TiO2 nanoparticles. The results showed that the DSSC made of black pomegranate bark was more efficient than the other cells due to its strong bonding with TiO2 nanoparticles. Longer electron lifetime, lower electron recombination, and lower...

متن کامل

The Construction and Comparison of Dye-Sensitized Solar Cells with Blackberry and N719 Dyes

In a dye-sensitized solar cell (DSSC), the amount of light absorption dependson the design of the pigments, which determines the strength of light absorption and theoptical range of the cell. In this paper, we have constructed and studied two fairly similarpattern of DSSCs in structure. The thickness of TiO2 used for both cells is taken to be 2μm. We have used an industrial N719 dye for one of ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2014